Kind of hard to list all the words that need to add 兒. In fact, 兒化音 is being used less and less in mordern standard Chinese over that past decades. Most commonly seen in Nouns. Whereas there are some certain words that definately need to add 兒.
1. Where it would differenciate the meaning of the words. Eg. 頭 (head), 頭兒 (leader, more commonly seen in the oral and Northern China dialects)
2. Where it would differenciate the part of speech of the words. Eg. 畫(v. draw) 畫兒(n. drawing); 堆(v. heap), 堆兒 (n. a pile of.../a stack of... ) Therefore, definately use "畫畫兒“ when they get toghether.
3. Where it may indicate intimacy Eg. calling the name of one's own puppy or children; 小河兒 (little stream)
Other than the above, most of the time, it won't affect the daily communication whether to add 兒 or not.
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