Both 多云 and 阴天 can be seen clouds in the sky. 1. 多云 more means the weather is a little sunny with some clouds but not to shining brightly, and the color of the sky is a little blue or brightly white. 2. 阴天 means you can not see the sun, there are some clouds in the sky, and the color of sky is dim white or gray, 阴天 is gloomier than 多云, sometimes it is like going to rain.